Removal of Clofibric, Salicylic and Gallic Acids from Aqueous Solutions by Adsorption on a Commercial Activated Carbon

Authors

  • N. Taoufik Université Hassan II de Casablanca, Faculté des Sciences et Techniques, Laboratoire de Chimie Physique et de Chimie Bioorganique, BP 146, 20650 Mohammedia, Morocco
  • A. Elmchaouri Université Hassan II de Casablanca, Faculté des Sciences et Techniques, Laboratoire de Chimie Physique et de Chimie Bioorganique, BP 146, 20650 Mohammedia, Morocco
  • S. Korili INAMAT - Department of Applied Chemistry, Los Acebos Building, Public University of Navarre, Campus of Arrosadia, E-31006 Pamplona, Spain
  • A. Gil INAMAT - Department of Applied Chemistry, Los Acebos Building, Public University of Navarre, Campus of Arrosadia, E-31006 Pamplona, Spain

DOI:

https://doi.org/10.12974/2311-8741.2018.06.2

Keywords:

Adsorption, kinetics, equilibrium, Activated Carbon, Pharmaceutical compounds.

Abstract

The adsorption behavior of three pharmaceutical compounds and widespread used drugs, namely, clofibric acid, salicylic acid and gallic acid from aqueous solutions was investigated using an activated carbon, as adsorbent. This study aims to evaluate the performance efficiency of the proposed adsorbent commercial activated carbon for eliminate these organic compounds.

The Freundlich, Langmuir, Temkin and Toth models were applied to the equilibrium data and in order to describe the adsorption behavior. It was found that the experimental data fitted well to the Langmuir model. It is also revealed that the adsorption of this compounds from the aqueous solutions on the activated carbon refer to the S-type by the Giles’s classification.

In order to investigate the mechanism of adsorption, kinetic data were modelled using the pseudo-first- and pseudo-second-order kinetic model. The results showed that kinetic data followed closely to the pseudo-second order model. 

References

Heberer T. Occurence, fate and removal of pharmaceutical residues in the aquatic environment: a review of recent research data. Toxicol Lett 2002; 131: 5-17. https://doi.org/10.1016/S0378-4274(02)00041-3

Kasprzyk-Hordern B, Dinsdale RM and Guwy AJ. The removal of pharmaceuticals, personal care products, endocrine disruptors and illicit drugs during wastewater treatment and its impact on the quality of receiving waters. Water Res 2009; 43: 363-80. https://doi.org/10.1016/j.watres.2008.10.047

Carucci A, Cappai G and Piredda M. Biodegradability and toxicity of pharmaceuticals in biological wastewater treatment plants. J Environ Sci Heal A 2006; 41: 1831-42. https://doi.org/10.1080/10934520600779000

Urase T and Kikuta T. Separate estimation of adsorption and degradation of pharmaceutical substances and estro-gens in the activated sludge process, Water Res 2005; 39: 1289- 300. https://doi.org/10.1016/j.watres.2005.01.015

Snyder SA, Adham S, Redding AM, Cannon FS, De Carolis J, Oppenheimer J, et al. Role of membranes and activated carbon in the removal of endocrine disruptors and pharmaceuticals. Desalination 2007; 202: 156-81. https://doi.org/10.1016/j.desal.2005.12.052

Benitez FJ, Real FJ, Acero JL, Leal AI and Garcia C. Gallic acid degradation in aqueous solutions by UV/H2O2 treatment, Fenton's reagent and the photo-Fenton system. J Hazard Mater 2005; B126: 31-9. https://doi.org/10.1016/j.jhazmat.2005.04.040

Adan C, Coronado JM, Bellod R, Soria J and Yamaoka H. Photochemical and photocatalytic degradation of salicylic acid with hydrogen peroxide over TiO2/SiO2 fibres. Appl Catal A: General 2006; 303: 199-206. https://doi.org/10.1016/j.apcata.2006.02.006

Kim IY, Kim KM, Yoon Y, Im JK and Zoh KD. Kinetics and degradation mechanism of clofibric acid and diclofenac in UV photolysis and UV/H2O2 reaction, Desal Water Treatment 2013; 52: 6211-8. https://doi.org/10.1080/19443994.2013.817507

Lindqvist N, Tuhkanen T and Kronberg L. Occurrence of acidic pharmaceuticals in raw and treated sewages and in receiving waters. Water Res 2005; 39: 2219-28. https://doi.org/10.1016/j.watres.2005.04.003

Essandoh M, Kunwar B, Pittman Jr CU, Mohan D and Mlsna T. Sorptive removal of salicylic acid and ibuprofen from aqueous solutions using pine wood fast pyrolysis biochar. Chem Eng J 2015; 265: 219-27. https://doi.org/10.1016/j.cej.2014.12.006

Chang EE, Wan JCh, Kim H, Liang CH, Dai YD and Chiang PC. Adsorption of selected pharmaceutical compounds onto activated carbon in dilute aqueous solutions exemplified by acetaminophen, diclofenac, and sulfamethoxazole. The Sci World J 2015; 2015.

Redding AM, Cannon FS, Snyder SA and Vanderford BJ. A QSAR-like analysis of the adsorption of endocrine disrupting compounds, pharmaceuticals, and personal care products on modified activated carbons. Water Res 2009; 43: 3849-61. https://doi.org/10.1016/j.watres.2009.05.026

Vergili I and Barlas H. Removal of selected pharmaceutical compounds from water by an organic polymer resin. J Sci Ind Res 2009; 68: 417-25.

Delgado LF, Charles P, Glucina K and Morlay C. The removal of endocrine disrupting compounds, pharmaceutically activated compounds and cyanobacterial toxins during drinking water preparation using activated carbon-A review. Sci Total Environ 2012; 435-436: 509-25. https://doi.org/10.1016/j.scitotenv.2012.07.046

Dabrowski A, Podkoscielny P, Hubicki Z and Barczak M. Adsorption of phenolic compounds by activated carbon – acritical review. Chemosphere 2005; 58: 1049-70. https://doi.org/10.1016/j.chemosphere.2004.09.067

Simazaki D, Fujiwara J, Manabe S, Matsuda M, Asami M, et al. Removal of selected pharmaceuticals by chlorination, coagulation–sedimentation and powdered activated carbon treatment. Water Sci Technol 2008; 58: 1129-35. https://doi.org/10.2166/wst.2008.472

Ternes TA, Suber J, Herrmann N, McDowell D, Ried A, et al. Ozonation: a tool for removal of pharmaceuticals, contrast media and musk fragrances from wastewater. Water Res 2003; 37: 1976-82. https://doi.org/10.1016/S0043-1354(02)00570-5

Bauerlein PS, ter Laak TL, Hofman-Caris RCHM, Voogt PD and Droge STJ. Removal of charged micro pollutants from water by ion-exchange polymers. Effects of competing electrolytes. Water Res 2012; 46: 5009-18. https://doi.org/10.1016/j.watres.2012.06.048

Schröder HFr, Tambosi JL, Sena RF, Moreira RFPM, José HJ, et al. The removal and degradation of pharmaceutical compounds during membrane bioreactor treatment. Water Sci Technol 2012; 65: 833-9. https://doi.org/10.2166/wst.2012.828

Yu ZR, Peldszus S and Huck PM. Adsorption characteristics of selected pharmaceuticals and an endocrine disrupting compound – naproxen, carbamazepine and nonylphenol- on activated carbon. Water Res 2008; 42: 2873-82. https://doi.org/10.1016/j.watres.2008.02.020

Gil A, Assis FCC, Albeniz S and Korili SA. Removal of dyes from wastewaters by adsorption on pillared clays. Chem Eng J 2011; 168: 1032-40. https://doi.org/10.1016/j.cej.2011.01.078

Otero M, Zabkova M and Rodrigues AE. Comparative study of the adsorption of phenol and salicylic acid from aqueous solution onto nonionic polymeric resins. Separ Purif Technol 2005; 45: 86-95. https://doi.org/10.1016/j.seppur.2005.02.011

Khenniche L and Aissani F. Characterization and utilization of activated carbons prepared from coffee residue for adsorptive removal of salicylic acid and phenol: Kinetic and isotherm study. Desal Water Treat 2009; 11: 192-203. https://doi.org/10.5004/dwt.2009.801

Carballa M, Omil F, Lema JM, Llompart M, Garcia-Jares C, et al. Behavior of pharmaceuticals, cosmetics and hormones in a sewage treatment plant. Water Res 2004; 38: 2918-26. https://doi.org/10.1016/j.watres.2004.03.029

Khetan SK and Collins TJ. Human pharmaceuticals in the aquatic an environment: a challenge to green chemistry. Chem Rev 2007; 107: 2319-64. https://doi.org/10.1021/cr020441w

Neuvonen P. Clinical pharmacokinetics of oral activated charcoal in acute intoxications. Clin Pharmaco kinet 1982; 7: 465-89. https://doi.org/10.2165/00003088-198207060-00001

Sui Q, Huang J, Liu Y, Chang X, Ji G, et al. Rapid removal of bisphenol A on highly ordered mesoporous carbon. J Environ Sci 2011; 23: 177-82. https://doi.org/10.1016/S1001-0742(10)60391-9

Chern J and Chien Y. Competitive adsorption of benzoic acid and p-nitrophenol onto activated carbon: isotherm and breakthrough curves. Water Res 2003; 37: 2347-56. https://doi.org/10.1016/S0043-1354(03)00038-1

Behera SK, Oh SY and Park HS. Sorptive removal of ibuprofen from water using selected soil minerals and activated carbon. Int J Environ Sci Technol 2012; 9: 85-94. https://doi.org/10.1007/s13762-011-0020-8

Ameta R, Benjamin S, Ameta A and Ameta SC. Photocatalytic degradation of organic pollutants: a review. Mater Sci Forum 2013; 734: 247-72. https://doi.org/10.4028/www.scientific.net/MSF.734.247

Diaz-Flores PE, Leyva-Ramos R, Guerrero-Coronado RM and Mendoza-Barron J. Adsorption of pentachlorophenol from aqueous solution onto activated carbon fiber. Ind Eng Chem Res 2006; 45: 330-6. https://doi.org/10.1021/ie050507o

Yan XM, Shi BY, Lu JJ, Feng CH, Wang DS and Tang HX. Adsorption and desorption of atrazine on carbon nanotubes. J Coll Interface Sci 2008; 321: 30-8. https://doi.org/10.1016/j.jcis.2008.01.047

Park Y, Sun Z, Ayoko GA and Frost RL. Bisphenol A sorption by organo-montmorillonite: Implications for the removal of organic contaminants from water. Chemosphere 2014; 107: 249-56. https://doi.org/10.1016/j.chemosphere.2013.12.050

Fauziah S, Draman S, Auni I, Azman B and Mohd N. Removal of paracetamol from aqueous solution by dried cellulose and activated carbon. ARPN J Eng Appl Sci 2015; 10: 9544-8.

Goyne KW, Chorover J, Kubicki JD, Zimmerman AR and Brantley SL. Sorption of the antibiotic ofloxacin to mesoporous and nonporous alumina and silica. J Colloid Interf Sci 2005; 283: 160-70. https://doi.org/10.1016/j.jcis.2004.08.150

Haghseresht F, Nouri S and Lu GQ. Effects of the solute ionization on the adsorption of aromatic compounds from dilute aqueous solutions by activated carbon. Langmuir 2002; 18: 1574-9. https://doi.org/10.1021/la010903l

Moreno-Castilla C. Adsorption of organic molecules from aqueous solutions on carbon materials. Carbon 2004; 42: 83- 94. https://doi.org/10.1016/j.carbon.2003.09.022

Andreozzi R, Marotta R and Nicklas P. Pharmaceuticals in STP effluents and their solar photodegradation in aquatic environment. Chemosphere 2003; 50: 1319-30. https://doi.org/10.1016/S0045-6535(02)00769-5

Uddin MT, Islam MS and Abedin MZ. Adsorption of phenol from aqueous solution by water hyacinth ash. J Eng Appl Sci 2007; 2: 11-7.

Tolmachev AM. Adsorption of gases, vapours and solutions: I. Thermodinamics of adsorption, Prot Metals Phys Chem Surf. 2010; 46: 170-83. https://doi.org/10.1134/S2070205110020024

Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 1918; 40: 1361- 403. https://doi.org/10.1021/ja02242a004

Ho YS and McKay G. Pseudo-second order model for sorption processes. Process Biochem 1999; 34: 451-65. https://doi.org/10.1016/S0032-9592(98)00112-5

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Published

2018-05-03

How to Cite

Taoufik, N., Elmchaouri, A., Korili, S., & Gil, A. (2018). Removal of Clofibric, Salicylic and Gallic Acids from Aqueous Solutions by Adsorption on a Commercial Activated Carbon. Journal of Environmental Science and Engineering Technology, 6, 9–20. https://doi.org/10.12974/2311-8741.2018.06.2

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